A new protection/activation strategy for the synthesis of naturally occurring and non-natural α-N-alkylamino acids

K. Burger; H. Schedel; J. Spengler

doi:10.1007/BF01388173

A new protection/activation strategy for the synthesis of naturally occurring and non-natural α-N-alkylamino acids

K. Burger
, H. Schedel
, J. Spengler

Leipzig University

Producción científica: Contribución a una revista › Artículo de revisión › revisión exhaustiva

4 Citas (Scopus)

Resumen

A new method for the preparation of N-methylamino acids and some of their derivatives starting from hexafluoroacetone protected amino acids is described. The new concept results in saving of steps compared to conventional protection/activation techniques. Protection and deprotection proceed without racemization.

Idioma original	Inglés
Páginas (desde-hasta)	287-295
Número de páginas	9
Publicación	Amino Acids
Volumen	16
N.º	3-4
DOI	https://doi.org/10.1007/BF01388173
Estado	Publicada - 1999
Publicado de forma externa	Sí

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title = "A new protection/activation strategy for the synthesis of naturally occurring and non-natural α-N-alkylamino acids",

abstract = "A new method for the preparation of N-methylamino acids and some of their derivatives starting from hexafluoroacetone protected amino acids is described. The new concept results in saving of steps compared to conventional protection/activation techniques. Protection and deprotection proceed without racemization.",

keywords = "α-N-methylamino acids, α-N-phosphinoylmethylamino acids, Amino acids, Hexafluoroacetone, Pro-Glu-chimeras, Pro-Tau-chimeras",

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T1 - A new protection/activation strategy for the synthesis of naturally occurring and non-natural α-N-alkylamino acids

AU - Burger, K.

AU - Schedel, H.

AU - Spengler, J.

PY - 1999

Y1 - 1999

N2 - A new method for the preparation of N-methylamino acids and some of their derivatives starting from hexafluoroacetone protected amino acids is described. The new concept results in saving of steps compared to conventional protection/activation techniques. Protection and deprotection proceed without racemization.

AB - A new method for the preparation of N-methylamino acids and some of their derivatives starting from hexafluoroacetone protected amino acids is described. The new concept results in saving of steps compared to conventional protection/activation techniques. Protection and deprotection proceed without racemization.

KW - α-N-methylamino acids

KW - α-N-phosphinoylmethylamino acids

KW - Amino acids

KW - Hexafluoroacetone

KW - Pro-Glu-chimeras

KW - Pro-Tau-chimeras

UR - https://www.scopus.com/pages/publications/0032969459

U2 - 10.1007/BF01388173

DO - 10.1007/BF01388173

M3 - Artículo de revisión

C2 - 10399017

AN - SCOPUS:0032969459

SN - 0939-4451

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SP - 287

EP - 295

JO - Amino Acids

JF - Amino Acids

IS - 3-4

ER -

A new protection/activation strategy for the synthesis of naturally occurring and non-natural α-N-alkylamino acids

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